Elements, Compounds and Mixtures Notes

Cambridge IGCSE Chemistry: Revision notes

Key facts

  • An element is made of only one type of atom.
  • A compound is two or more elements chemically combined in fixed proportions; it has different properties from its elements.
  • A mixture is not chemically combined; each part keeps its properties and the composition can vary.
  • An atom has a nucleus of protons and neutrons, with electrons in shells.
  • Shells fill from the inside: 2, 8, 8.

Three kinds of substance

Elements have one type of atom, compounds are chemically bonded elements, and mixtures are not chemically combined.

A compound has different properties from the elements it is made from. A mixture keeps the properties of its parts, and its composition can vary.

Element

Made of:
One type of atom
Separated by:
Cannot be broken down into simpler substances

Compound

Made of:
Two or more elements chemically combined in fixed proportions
Separated by:
Only a chemical reaction that breaks the bonds

Mixture

Made of:
Two or more substances not chemically combined
Separated by:
Physical methods such as filtration or distillation

Pure substance

Mixture

A pure substance contains one kind of particle; a mixture contains different kinds, not chemically joined.

Which can be separated by a physical method?

Mixture or compound

Mixed iron and sulfur can be separated with a magnet, but once heated they form a new compound.

Iron and sulfur powders stay as separate substances when mixed, so a magnet pulls out the iron. Heating makes the two elements react to form iron sulfide, a new compound with different properties that the magnet no longer attracts.

  1. 1

    Mix

    iron and sulfur powders stay as separate substances

  2. 2

    Separate

    a magnet pulls out the iron, so it is a mixture

  3. 3

    Heat

    the two elements react

  4. 4

    Iron sulfide

    a new compound with different properties, not attracted by a magnet

Iron and sulfur: mixture then compound

After iron and sulfur are heated together, why is the magnet no longer able to remove the iron?

Inside the atom

Every atom has a tiny dense nucleus of protons and neutrons, surrounded by electrons in shells.

The nucleus contains protons and neutrons; electrons move around it in shells (energy levels). Almost all the mass is in the nucleus, but almost all the volume is empty space.

The neutral atom has equal numbers of protons and electrons.

C6p 6n

Carbon

2,4

A carbon atom: 6 protons, 6 neutrons and 6 electrons in shells 2,4.

Proton

  • Relative charge +1
  • Relative mass 1

Neutron

  • Relative charge 0
  • Relative mass 1

Electron

  • Relative charge −1
  • Relative mass very small (often taken as 0)

Which particle has a relative charge of −1?

Proton and mass number

Proton number identifies the element; mass number counts protons plus neutrons.

Proton (atomic) number is the number of protons in the nucleus and defines the element. Mass (nucleon) number is the number of protons plus neutrons.

Na11p 12n

Sodium

2,8,1

Sodium: proton number 11, mass number 11 + 12 = 23.
  • Neutronsmass number − proton number

Worked example

An atom of sodium has proton number 11 and mass number 23. How many protons, electrons and neutrons does it have?

An atom has proton number 17 and mass number 35. How many neutrons?

Electrons in shells

Electrons fill shells from the nucleus outwards: the first three hold 2, 8 and 8.

The electronic configuration lists the electrons in each shell. An atom with 13 electrons is 2,8,3. The configuration of a neutral atom comes from its proton number, which equals its number of electrons.

Na11p 12n

Sodium

2,8,1

Cl17p 18n

Chlorine

2,8,7

Electron shells fill from the inside out: sodium is 2,8,1 and chlorine is 2,8,7.
1234567012341H2He3Li4Be5B6C7N8O9F10Ne11Na12Mg13Al14Si15P16S17Cl18Ar19K20Ca
Na11p

2,8,1

Group 1
1 outer electron
Period 3
3 shells
Tap any element from hydrogen to calcium.

What is the electronic configuration of an atom with 13 electrons?

Try an exam question

Describe the differences between a compound and a mixture, using iron and sulfur as an example.

[4 marks]

That's the notes covered.

Carry on to the next subtopic.