Key facts

  • Anhydrous cobalt(II) chloride turns blue → pink with water; anhydrous copper(II) sulfate turns white → blue.
  • Pure water melts at 0 °C and boils at 100 °C; impurities change these.
  • Distilled water is made by boiling and condensing.
  • Water treatment: sedimentation, filtration, activated carbon, chlorination.
  • Fertiliser run-off (nitrates, phosphates) causes excess algal growth.

Testing for water

Anhydrous cobalt(II) chloride and anhydrous copper(II) sulfate both change colour when they become hydrated.

Both tests rely on a colour change as the substance becomes hydrated; the change can be reversed by removing the water.

  1. 1

    Anhydrous solid

    cobalt(II) chloride is blue; copper(II) sulfate is white

  2. 2

    Add water

    the solid becomes hydrated

  3. 3

    Hydrated solid

    cobalt(II) chloride turns pink; copper(II) sulfate turns blue

  4. 4

    Remove the water

    the original colour returns

Then back to step 1

The colour change is reversible when the water is removed.

Without water

Cobalt(II) chloride:
Blue
Copper(II) sulfate:
White

With water

Cobalt(II) chloride:
Pink
Copper(II) sulfate:
Blue

Anhydrous copper(II) sulfate turns from white to:

Purity of water

Pure water melts at exactly 0 °C and boils at 100 °C.

Dissolved impurities lower the melting point and raise the boiling point, so any deviation shows that dissolved substances are present. A sample boiling at 102 °C is not pure.

96979899100101102103104105106Pure: 100Sample: 102
Boiling point of water samples (°C)

A water sample boils at 102 °C. It is:

Distilled water

It is pure, so it does not interfere with reactions or measurements.

Distilled water has virtually no dissolved or suspended impurities, prevents unwanted side reactions and gives consistent, repeatable results. Tap water contains dissolved minerals and chlorine that can affect reaction rates, products and measurements.

  1. 1

    Boil the water

    it changes to steam

  2. 2

    Impurities stay behind

    they do not evaporate

  3. 3

    Condense the steam

    cool it back to a liquid

  4. 4

    Collect distilled water

    pure liquid water

Making distilled water

How is distilled water made?

Contaminants

Natural water carries dissolved and suspended substances, some beneficial and some harmful.

Beneficial substances support aquatic ecosystems; harmful ones damage water quality and risk health.

  1. 1

    Fertiliser runs off fields

    nitrates and phosphates enter the water

  2. 2

    Excess algal growth

  3. 3

    Dissolved oxygen is used up

    oxygen depletion

  4. 4

    Fish and other life are harmed

    fish need dissolved oxygen to breathe

Example of a harmful contaminant: fertiliser run-off.

Source

Dissolved oxygen:
Atmosphere, aquatic plants
Metal compounds:
Rock weathering, soil minerals
Plastics:
Human pollution
Sewage:
Human waste, urban run-off
Nitrates and phosphates:
Fertiliser run-off

Effect

Dissolved oxygen:
Beneficial: fish need it to breathe
Metal compounds:
Mixed: calcium and magnesium essential; lead and mercury toxic
Plastics:
Harmful: damage organisms, enter food chains
Sewage:
Harmful: disease-causing microbes
Nitrates and phosphates:
Harmful: excess algal growth, oxygen depletion

Which contaminant is beneficial?

Water treatment

Settling and filtering remove solids, carbon removes taste and odour, and chlorine kills microbes.

Heavy solids settle in tanks (sedimentation), then sand and gravel filters remove remaining solids. Activated carbon, with a large surface area, adsorbs tastes, odours and some chemicals. Chlorine kills bacteria and viruses, protecting against cholera and typhoid, and a little stays in the water as it travels through pipes.

  1. 1

    Sedimentation

    heavy solids settle out

  2. 2

    Filtration

    sand and gravel remove fine solids

  3. 3

    Activated carbon

    removes tastes and odours

  4. 4

    Chlorination

    kills harmful microbes

Water treatment

What is chlorine added to water for?

Try an exam question

Describe a chemical test for water and a physical test to show that a sample of water is pure.

[3 marks]

That's the notes covered.

Carry on to the next subtopic.