Conservation of Mass Notes

Oxford AQA IGCSE Chemistry: Revision notes

Key facts

  • Reactions can be shown as word equations or balanced symbol equations.
  • State symbols: (s) solid, (l) liquid, (g) gas, (aq) dissolved in water.
  • No atoms are lost or made in a reaction, only rearranged.
  • Total mass of reactants = total mass of products.
  • Apparent mass changes in open containers are due to a gas entering or leaving.

Showing reactions

Use a word equation to name substances and a balanced symbol equation to show the atoms.

Both show reactants on the left and products on the right, with an arrow between.

00.511.52Mg atomsO atomsElementNumber of atoms
  • Reactants
  • Products
2Mg + O₂ → 2MgO: a balanced equation has the same number of each atom on both sides.

Word equation

Example:
magnesium + oxygen → magnesium oxide
Shows:
Names the substances

Balanced symbol equation

Example:
2 Mg+OX2→2 MgO\ce{2Mg + O2 -> 2MgO}
Shows:
Shows the exact atoms

Which is a balanced symbol equation?

State symbols

State symbols in brackets after each formula show the physical state.

For example HCl(aq)+NaOH(aq)→NaCl(aq)+HX2O(l)\ce{HCl(aq) + NaOH(aq) -> NaCl(aq) + H2O(l)}. State symbols are shown at the temperature of the reaction.

(s)

(l)

(g)

(aq)

State symbols: solid (s), liquid (l), gas (g) and dissolved in water (aq).

(s)

Meaning:
Solid
Example:
Mg(s)\ce{Mg(s)}

(l)

Meaning:
Liquid
Example:
HX2O(l)\ce{H2O(l)}

(g)

Meaning:
Gas
Example:
COX2(g)\ce{CO2(g)}

(aq)

Meaning:
Dissolved in water
Example:
NaCl(aq)\ce{NaCl(aq)}

What does (aq) mean in NaCl(aq)\ce{NaCl(aq)}?

The law

Atoms are rearranged in a reaction, so the total mass of products equals the total mass of reactants.

No atoms are lost or made. A balanced equation shows equal numbers of each atom on both sides, and this principle underlies all reacting-mass calculations.

010203040MagnesiumOxygenTotal reactantsMagnesium oxideSubstanceMass (g)
Magnesium (24 g) burns with oxygen (16 g) to give magnesium oxide: 24 + 16 = 40 g.
  • Mass of reactants= mass of products

Worked example

3 g of magnesium burns completely in 2 g of oxygen. What mass of magnesium oxide forms?

A student heats a metal carbonate in an open crucible and the mass goes down. Why?

Apparent mass changes

A gas entering or leaving an open container changes the mass you measure.

Mass increases when magnesium burns because it gains oxygen from the air. Mass decreases when a carbonate is heated because carbon dioxide escapes. Overall mass is still conserved.

020406080100Mg beforeMg after burningCaCO₃ beforeCaO leftSubstanceMass (g)
Open container: Mg gains mass from O₂; CaCO₃ (100 g) loses CO₂ (44 g), leaving 56 g of CaO.

Magnesium burns in air

Measured mass:
Mass goes up
Reason:
Oxygen gas is gained

Carbonate heated in open crucible

Measured mass:
Mass goes down
Reason:
Carbon dioxide escapes

Magnesium is burned in air and the mass of the solid increases. Why?

Try an exam question

5.0 g of calcium carbonate is heated strongly in an open crucible. The mass of the solid left is less than 5.0 g. Explain why.

[3 marks]

That's the notes covered.

Carry on to the next subtopic.