Energy Level DiagramsOxford AQA IGCSE Chemistry: Revision notes
Section 1
What does an energy level diagram show?
An energy level diagram is a simple graph plotting energy (vertical axis) against the progress of the reaction (horizontal axis). It shows:
- The energy of the reactants (starting level)
- The energy of the products (finishing level)
- The activation energy — the size of the 'hump' between reactants and the peak of the curve
- The overall energy change (ΔH) of the reaction — the vertical distance between the reactant and product energy levels
Section 2
How does an exothermic reaction look on the diagram?
In an exothermic reaction, the products have less energy than the reactants, because energy has been transferred to the surroundings.
- The product energy level is drawn below the reactant energy level
- ΔH is negative
- Examples: combustion, many oxidation reactions, neutralisation
Always state whether the product line is above or below the reactant line — examiners award marks for this, not just the word 'exothermic'.
Section 3
How does an endothermic reaction look on the diagram?
In an endothermic reaction, the products have more energy than the reactants, because energy has been taken in from the surroundings.
- The product energy level is drawn above the reactant energy level
- ΔH is positive
- Examples: thermal decomposition reactions
Section 4
What is activation energy?
The activation energy is the minimum amount of energy that colliding particles must have for a reaction to occur. On the diagram it is shown as the height of the curve above the reactants' energy level — the 'hump' the reaction pathway must climb over before it can fall to the products' energy level (or continue rising, for an endothermic reaction).
Think of activation energy as a small hill a ball must be pushed over before it can roll down (exothermic) or up (endothermic) to its final energy level.
Section 5
How does a catalyst affect the diagram?
A catalyst provides an alternative reaction pathway with a lower activation energy. On the diagram, this is shown as a lower, flatter hump between the reactants and products.
- The overall energy change (ΔH) stays exactly the same — only the activation energy is reduced
- More particles will have enough energy to react, so the reaction rate increases
Do not draw a catalyst as changing the energy of the reactants or products — it only changes the height of the activation energy hump.
Must Know
- Energy level diagrams show reactant energy, product energy, activation energy, and overall energy change (ΔH)
- Exothermic: products lower than reactants, ΔH negative
- Endothermic: products higher than reactants, ΔH positive
- Activation energy is the minimum energy needed for particles to react, shown as the hump
- A catalyst lowers the activation energy hump but does not change ΔH
- The overall energy change is the vertical gap between reactant and product levels
That's the notes covered.
Carry on to the next subtopic.