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Ideal gasesAQA A-Level Physics: Flashcards

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State Boyle's law.

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State Boyle's law.
For a fixed mass of gas at constant temperature, pVpV is constant.
State Charles's law.
For a fixed mass of gas at constant pressure, V/TV/T is constant, with TT in kelvin.
What is absolute zero?
0 K or −273 °C, the lowest possible temperature.
How do you convert °C to K?
Add 273: T/K=θ/∘C+273T/\text{K} = \theta/{}^\circ\text{C} + 273.
State the ideal gas equation in terms of moles.
pV=nRTpV = nRT
State the ideal gas equation in terms of molecules.
pV=NkTpV = NkT
How are RR and kk related?
k=R/NAk = R/N_A
What is the value of the Boltzmann constant?
1.38×10−231.38 \times 10^{-23} J K⁻¹
How is the number of molecules related to the number of moles?
N=nNAN = nN_A
How is molecular mass related to molar mass?
m=M/NAm = M/N_A
State the equation for work done by a gas at constant pressure.
W=pΔVW = p\Delta V
What graph confirms Boyle's law?
pp against 1/V1/V, a straight line through the origin.
Why wait before taking a reading in Boyle's law experiment?
Compression heats the gas, so wait for it to return to the temperature of the surroundings.

Exam questions on Ideal gases

  1. A rigid sealed cylinder of volume 2.0 × 10⁻² m³ contains 0.80 mol of an ideal gas at a temperature of 300 K (27 °C). The molar gas constant is 8.31 J mol⁻¹ K⁻¹ and the Avogadro constant is 6.02 × 10²³ mol⁻¹.
    Calculate the number of molecules of gas in the cylinder.2 marks
  2. A student investigates a fixed mass of dry air trapped in a glass tube by a short thread of oil. In the first experiment the pressure on the air is varied using a pump while the temperature is kept constant. In the second experiment the tube is heated in a water bath at atmospheric pressure.
    In the first experiment, the student waits for a short time after changing the pressure before each reading of the volume. Explain why.2 marks
  3. A gas is trapped in a cylinder by a frictionless piston and kept at a constant pressure of 1.0 × 10⁵ Pa. Its initial volume is 2.0 × 10⁻³ m³ at a temperature of 290 K. The gas is heated slowly until its volume is 5.0 × 10⁻³ m³. Treat the gas as ideal, with RR = 8.31 J mol⁻¹ K⁻¹.
    Calculate the work done by the gas as it expands.3 marks
See the full worksheet

Written by the Exaim team, led by Shaun Daswani (Head of Upper Secondary, Improve ME Institute; MSc Financial Mathematics, Imperial College London; BSc, UCL) and Jason Daswani (operational lead, Improve ME Institute; LSE).