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Bronsted-Lowry acids and basesAQA A-Level Chemistry: Mind map

Definitions
Proton transfer
Examples

Brønsted–Lowry

Acids and bases

AcidBaseH⁺
Conjugate pairs
Equilibria
Exam tips

Exam questions on Bronsted-Lowry acids and bases

  1. Ammonia gas dissolves in water to form a solution that turns red litmus blue. The equilibrium in the solution can be written as NH₃ + H₂O ⇌ NH₄⁺ + OH⁻.
    Explain, in terms of proton transfer, why ammonia acts as a base in water.2 marks
  2. Sodium hydrogencarbonate is added to water. The hydrogencarbonate ion, HCO₃⁻, reacts with acids and with alkalis according to the equations: (1) HCO₃⁻ + H₃O⁺ → H₂CO₃ + H₂O and (2) HCO₃⁻ + OH⁻ → CO₃²⁻ + H₂O.
    Use the two equations to explain why the hydrogencarbonate ion can act as both an acid and a base.2 marks
  3. Two acid–base reactions are studied. Reaction 1: hydrogen chloride gas and ammonia gas meet in a dry tube and form a white smoke of solid ammonium chloride, HCl(g) + NH₃(g) → NH₄Cl(s). Reaction 2: in the nitrating mixture used to make nitrobenzene, concentrated nitric acid is mixed with concentrated sulfuric acid, HNO₃ + H₂SO₄ ⇌ H₂NO₃⁺ + HSO₄⁻.
    Explain, in terms of proton transfer, why Reaction 1 is an acid–base reaction, identifying the acid and the base.3 marks
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Written by the Exaim team, led by Shaun Daswani (Head of Upper Secondary, Improve ME Institute; MSc Financial Mathematics, Imperial College London; BSc, UCL) and Jason Daswani (operational lead, Improve ME Institute; LSE).