Reactions of aldehydes and ketonesAQA A-Level Chemistry: Mind map
Carbonyl group
Oxidation
Aldehydes and ketones
Oxidation and reduction
C=OTestsNaBH₄
Tollens' and Fehling's
Reduction
Mechanism
Exam questions on Reactions of aldehydes and ketones
- A technician has two unlabelled colourless liquids, one of which is propanal and the other propanone. She warms a sample of each separately with Tollens' reagent and with Fehling's solution in a hot water bath.State what is observed when propanone is tested with each reagent, and explain why propanal reacts differently.2 marks
- A chemist reduces a sample of butanal and a sample of butanone separately, using NaBH₄ in aqueous solution at room temperature.Write an overall equation for the reduction of butanal, using [H] to represent the reductant, and name the type of mechanism.2 marks
- Two isomeric carbonyl compounds, pentanal and pentan-2-one, are each treated with NaBH₄ in aqueous solution. The organic products are then separated and identified.Identify the organic product formed from each carbonyl compound, and state the class of alcohol in each case.3 marks
Written by the Exaim team, led by Shaun Daswani (Head of Upper Secondary, Improve ME Institute; MSc Financial Mathematics, Imperial College London; BSc, UCL) and Jason Daswani (operational lead, Improve ME Institute; LSE).