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Buffer solutionsEdexcel International A Level Chemistry: Flashcards

What these 13 flashcards ask

  • What is a buffer solution?
  • What does an acidic buffer contain?
  • How does an ethanoic acid buffer remove added H⁺?
  • How does it remove added OH⁻?
  • Write the formula for [H⁺] in a buffer.
  • What is the pH of a buffer with [HA] = [A⁻]?
  • How do you find the ratio needed for a buffer of given pH?
  • Why can amounts replace concentrations in buffer calculations?
  • What is the half-neutralisation point?
  • How is Ka found from a titration curve?
  • Which buffer keeps blood at about pH 7.4?
  • Why must the pH of blood stay constant?
  • Why are buffers used in foods?

Exam questions on Buffer solutions

  1. A technician prepares solutions containing ethanoic acid and sodium ethanoate. The Ka of ethanoic acid is 1.74 × 10⁻⁵ mol dm⁻³, so its pKa is 4.76.
    Explain how a buffer made from ethanoic acid and sodium ethanoate resists a change in pH when a small amount of hydrochloric acid is added.2 marks
  2. Human blood is kept at a pH of about 7.4. This is maintained largely by a buffer system based on carbonic acid, H₂CO₃, and hydrogencarbonate ions, HCO₃⁻.
    Explain why it is important that the pH of blood remains almost constant, and how the buffer achieves this.2 marks
  3. A technician needs 500 cm³ of a buffer solution of pH 5.00. The final buffer must contain ethanoic acid at a concentration of 0.500 mol dm⁻³, and the conjugate base is supplied by solid sodium ethanoate, CH₃COONa (M = 82.0 g mol⁻¹). The Ka of ethanoic acid is 1.74 × 10⁻⁵ mol dm⁻³.
    Calculate the mass of sodium ethanoate needed.3 marks
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Written by the Exaim team, led by Shaun Daswani (Head of Upper Secondary, Improve ME Institute; MSc Financial Mathematics, Imperial College London; BSc, UCL) and Jason Daswani (operational lead, Improve ME Institute; LSE).