The mole, concentration and empirical formulaeEdexcel International A Level Chemistry: Flashcards
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What is the Avogadro constant?
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- What is the Avogadro constant?
- 6.02 x 10^23 mol-1, the number of particles in one mole.
- How do you convert mass to amount in moles?
- amount (mol) = mass (g) / molar mass (g mol-1).
- How do you find the number of particles from an amount?
- Number = amount (mol) x 6.02 x 10^23.
- How many ions are in 0.100 mol of NaCl?
- 0.200 mol of ions, so 0.200 x 6.02 x 10^23 = 1.20 x 10^23 ions.
- Write the equation for concentration in mol dm-3.
- concentration = amount (mol) / volume (dm3).
- How do you convert cm3 to dm3?
- Divide by 1000.
- How do you convert a concentration in mol dm-3 to g dm-3?
- Multiply by the molar mass (g mol-1).
- What is the concentration, in mol dm-3, of 0.0250 mol in 500 cm3?
- 0.0250 / 0.500 = 0.0500 mol dm-3.
- State the four steps to find an empirical formula.
- Masses or percentages, divide by Ar to get moles, divide by the smallest, multiply to whole numbers if needed.
- Convert the mole ratio 1 : 1.5 to whole numbers.
- Multiply by 2 to give 2 : 3.
- How do you find the molecular formula from the empirical formula?
- Divide the relative molecular mass by the empirical formula mass to get n, then multiply the empirical formula by n.
- In combustion analysis, where does the carbon in a compound end up?
- In the carbon dioxide: n(C) = n(CO2).
- How do you find n(H) from the water produced in combustion?
- n(H) = 2 x n(H2O), because each water molecule has two hydrogen atoms.
Exam questions on The mole, concentration and empirical formulae
- A technician weighs 5.85 g of sodium chloride, NaCl (molar mass 58.5 g mol⁻¹), dissolves it in water and makes the solution up to 250 cm³. The Avogadro constant, L, is 6.02 × 10²³ mol⁻¹.Calculate the concentration of the solution in mol dm⁻³ and in g dm⁻³.2 marks
- A laboratory stock bottle holds 500 cm³ of sulfuric acid of concentration 0.250 mol dm⁻³. The molar mass of sulfuric acid, H₂SO₄, is 98.1 g mol⁻¹.Calculate the mass of sulfuric acid needed to make 2.50 dm³ of solution of the same concentration.2 marks
- A student analyses two compounds. Compound P, an oxide of iron, contains 2.10 g of iron and 0.90 g of oxygen. Compound Q is a hydrocarbon with relative molecular mass 70.0 that contains 85.7% carbon by mass. Relative atomic masses: H = 1.0, C = 12.0, O = 16.0, Fe = 55.8.Use the data to calculate the empirical formula of compound P.3 marks
Written by the Exaim team, led by Shaun Daswani (Head of Upper Secondary, Improve ME Institute; MSc Financial Mathematics, Imperial College London; BSc, UCL) and Jason Daswani (operational lead, Improve ME Institute; LSE).