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Gas volumes and the ideal gas equationEdexcel International A Level Chemistry: Flashcards

What these 13 flashcards ask

  • What is the molar volume of a gas at rtp?
  • What does rtp stand for and what are its values?
  • State the ideal gas equation with the units of each term.
  • Convert 85.0 cm3 to m3.
  • Convert 2.50 dm3 to m3.
  • Convert 101 kPa to Pa.
  • How do you convert from °C to K?
  • Rearrange pV = nRT to give the amount of gas.
  • How do you find molar mass from gas data?
  • What happens to the pressure of a fixed amount of gas at constant volume if the kelvin temperature doubles?
  • In Core Practical 1, why is excess acid used?
  • In Core Practical 1, how is the molar volume calculated?
  • Give two reasons why the volume of gas in Core Practical 1 might be too low.

Exam questions on Gas volumes and the ideal gas equation

  1. A student reacts 0.120 g of magnesium ribbon with an excess of dilute hydrochloric acid and collects the hydrogen in a gas syringe at room temperature and pressure (rtp). The molar volume of a gas at rtp is 24.0 dm³ mol⁻¹. The relative atomic mass of magnesium is 24.3.
    The student collects only 108 cm³ of hydrogen. Suggest two reasons why the measured volume is less than the calculated volume.2 marks
  2. A gas cylinder of fixed volume 2.50 dm³ contains 4.00 g of methane, CH₄ (molar mass 16.0 g mol⁻¹), at 300 K. Take R = 8.31 J K⁻¹ mol⁻¹ and the molar volume at rtp as 24.0 dm³ mol⁻¹.
    Calculate the volume the methane would occupy at rtp and use this to state whether the gas in the cylinder is at a higher or lower pressure than atmospheric pressure.2 marks
  3. A volatile liquid X is one of propanone (C₃H₆O), diethyl ether (C₄H₁₀O) or hexane (C₆H₁₄). A sample of mass 0.205 g is vaporised completely in a gas syringe and occupies 85.0 cm³ at 373 K and a pressure of 101 kPa. Take R = 8.31 J K⁻¹ mol⁻¹. Relative atomic masses: H = 1.0, C = 12.0, O = 16.0.
    Calculate the amount, in mol, of X in the gas syringe.3 marks
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Written by the Exaim team, led by Shaun Daswani (Head of Upper Secondary, Improve ME Institute; MSc Financial Mathematics, Imperial College London; BSc, UCL) and Jason Daswani (operational lead, Improve ME Institute; LSE).