Equilibrium constants Kc and KpEdexcel International A Level Chemistry: Mind map
Kc expression
Heterogeneous
Kc and Kp
Equilibrium constants
KcKpUnits
Kp
From data
Units
Exam questions on Equilibrium constants Kc and Kp
- In the Haber process nitrogen and hydrogen react reversibly: N₂(g) + 3H₂(g) ⇌ 2NH₃(g). A sealed vessel is held at 700 K until equilibrium is reached. The equilibrium concentrations are: N₂ 0.40 mol dm⁻³, H₂ 1.20 mol dm⁻³ and NH₃ 0.60 mol dm⁻³.Calculate the value of Kc at 700 K, including units.2 marks
- Carbon dioxide reacts with hot carbon: C(s) + CO₂(g) ⇌ 2CO(g). Excess solid carbon is held in a closed vessel at 1000 K and the total pressure at equilibrium is 2.0 atm. The gas mixture at equilibrium contains 0.30 mol of CO₂ and 0.90 mol of CO.Calculate Kp at 1000 K, including units.2 marks
- Dinitrogen tetraoxide dissociates in a sealed flask: N₂O₄(g) ⇌ 2NO₂(g). A student places 0.250 mol of N₂O₄ in a 5.00 dm³ flask at 373 K. At equilibrium 0.050 mol of N₂O₄ remains and the total pressure in the flask is 2.75 atm.Calculate Kc at 373 K, including units.3 marks
Written by the Exaim team, led by Shaun Daswani (Head of Upper Secondary, Improve ME Institute; MSc Financial Mathematics, Imperial College London; BSc, UCL) and Jason Daswani (operational lead, Improve ME Institute; LSE).