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Alkenes and geometric isomerismEdexcel International A Level Chemistry: Mind map

Alkenes
Sigma and pi

Alkenes and isomerism

C=C, restricted rotation, E-Z

CₙH₂ₙσ + πE / Z
Restricted rotation
cis / trans
E-Z

Exam questions on Alkenes and geometric isomerism

  1. A student studies hydrocarbons with a C=C double bond and builds models of several of them to compare their structures.
    Describe how the carbon–carbon double bond in an alkene is made up of a sigma bond and a pi bond.2 marks
  2. A chemist is explaining why some alkenes exist as pairs of isomers that cannot be interconverted at room temperature, and how these isomers are named.
    Explain why pent-1-ene does not show geometric isomerism.2 marks
  3. In an A Level class, but-2-ene and a halogenated alkene are used to illustrate geometric isomerism and the E-Z naming system.
    But-2-ene, CH₃CH=CHCH₃, shows geometric isomerism. Explain why, and name the two isomers using the E-Z system.3 marks
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Written by the Exaim team, led by Shaun Daswani (Head of Upper Secondary, Improve ME Institute; MSc Financial Mathematics, Imperial College London; BSc, UCL) and Jason Daswani (operational lead, Improve ME Institute; LSE).