All flashcards topics

Kw and pH of basesEdexcel A-Level Chemistry: Flashcards

What these 13 flashcards ask

  • Write the expression for Kw
  • Value of Kw at 298 K
  • Units of Kw
  • Define pKw
  • Relationship between pH, pOH and pKw
  • Why is [H2O] not in the Kw expression?
  • How do you find [H^+] in a strong base solution?
  • [OH^-] in 0.0150 mol dm⁻³ Ba(OH)₂
  • pH of 0.0250 mol dm⁻³ NaOH at 298 K
  • Effect of a tenfold dilution on the pH of a strong base
  • Why does Kw increase with temperature?
  • Is water at 323 K (Kw = 5.48 × 10⁻¹⁴) neutral?
  • What is the pH of neutral water in terms of pKw?

Exam questions on Kw and pH of bases

  1. A technician prepares a 0.0250 mol dm⁻³ solution of sodium hydroxide, a strong base, for a cleaning product. All measurements are at 298 K, where the ionic product of water, KwK_w, is 1.00 × 10⁻¹⁴ mol² dm⁻⁶.
    Calculate the pH of the sodium hydroxide solution.2 marks
  2. A water-treatment plant dissolves barium hydroxide, Ba(OH)₂, a strong base, to make a 0.0150 mol dm⁻³ solution at 298 K, where KwK_w = 1.00 × 10⁻¹⁴ mol² dm⁻⁶.
    Calculate the pH of the barium hydroxide solution.2 marks
  3. The ionic product of water varies with temperature. At 298 K, KwK_w = 1.00 × 10⁻¹⁴ mol² dm⁻⁶. At 323 K (50 °C), KwK_w = 5.48 × 10⁻¹⁴ mol² dm⁻⁶. A student measures the pH of pure water at 323 K with a calibrated meter.
    Calculate the pH of pure water at 323 K.3 marks
See the full worksheet

Written by the Exaim team, led by Shaun Daswani (Head of Upper Secondary, Improve ME Institute; MSc Financial Mathematics, Imperial College London; BSc, UCL) and Jason Daswani (operational lead, Improve ME Institute; LSE).