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The equilibrium constant KcEdexcel A-Level Chemistry: Mind map

The expression
Homogeneous

Kc

Equilibrium constant expression

products over reactantsequilibrium concentrations
Heterogeneous
Changing the equation
Exam tips

Exam questions on The equilibrium constant Kc

  1. Iron(III) ions react with thiocyanate ions in aqueous solution to form a blood-red complex ion: Fe³⁺(aq) + SCN⁻(aq) ⇌ [Fe(SCN)]²⁺(aq). A student studies the equilibrium mixture.
    The equation is rewritten as 2Fe³⁺(aq) + 2SCN⁻(aq) ⇌ 2[Fe(SCN)]²⁺(aq). Deduce the expression for Kc for this equation and state how it is related to Kc for the original equation.2 marks
  2. Calcium carbonate decomposes when heated strongly in a sealed container: CaCO₃(s) ⇌ CaO(s) + CO₂(g). A student investigates this heterogeneous equilibrium.
    Deduce the expression for Kc for the equilibrium 3Fe(s) + 4H₂O(g) ⇌ Fe₃O₄(s) + 4H₂(g).2 marks
  3. Methanol is manufactured from carbon monoxide and hydrogen: CO(g) + 2H₂(g) ⇌ CH₃OH(g). All three substances are gases.
    Deduce the expression for Kc for the formation of methanol. Deduce the expression for Kc' for the decomposition of methanol, CH₃OH(g) ⇌ CO(g) + 2H₂(g), and state how Kc' is related to Kc.3 marks
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Written by the Exaim team, led by Shaun Daswani (Head of Upper Secondary, Improve ME Institute; MSc Financial Mathematics, Imperial College London; BSc, UCL) and Jason Daswani (operational lead, Improve ME Institute; LSE).