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Isomerism: structural and E/ZEdexcel A-Level Chemistry: Mind map

Structural isomers
Chain and position

Isomerism

Structural and E/Z

structuralstereoE/Z
Functional group
E/Z isomerism
Labelling

Exam questions on Isomerism: structural and E/Z

  1. A chemist is cataloguing the isomers of the alkane C₅H₁₂ and of the haloalkane C₄H₉Br.
    Give the IUPAC names of the two branched isomers of C₅H₁₂.2 marks
  2. A student is studying alkenes with the molecular formulae C₄H₈ and C₅H₁₀, and how the arrangement of groups around the carbon-carbon double bond affects their properties.
    Explain what causes E/Z isomerism and state the condition on the groups attached to the C=C bond for a molecule to show it.2 marks
  3. Alkenes with the molecular formula C₅H₁₀ are used as models to study isomerism. Ignore cyclic compounds in this question.
    Give the structural formula and name of each unbranched alkene with molecular formula C₅H₁₀. State which one shows E/Z isomerism, with a reason.3 marks
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Written by the Exaim team, led by Shaun Daswani (Head of Upper Secondary, Improve ME Institute; MSc Financial Mathematics, Imperial College London; BSc, UCL) and Jason Daswani (operational lead, Improve ME Institute; LSE).