Rate-determining step and reaction mechanisms

Rate-determining step and reaction mechanisms Quiz

Edexcel A-Level Chemistry: Quiz

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5 questions, one answer each

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  1. 1. A reaction has rate = k[A][B]. Which slow step is consistent with this?

    • A. 2A → X
    • B. A + B → X
    • C. A + 2B → X
    • D. B → X
  2. 2. In the acid-catalysed iodination of propanone, iodine is zero order. What does this show?

    • A. Iodine is a catalyst
    • B. Iodine is in the rate-determining step
    • C. Iodine reacts in a fast step after the rate-determining step
    • D. Iodine does not react at all
  3. 3. A tertiary halogenoalkane is hydrolysed with rate = k[RBr]. What is the mechanism?

    • A. SN2
    • B. SN1
    • C. Free-radical substitution
    • D. Elimination only
  4. 4. The mechanism of a reaction is: step 1 (slow) A + B → C + D; step 2 (fast) C + B → E. What is the overall equation?

    • A. A + 2B → D + E
    • B. A + B → E
    • C. A + B → C + D
    • D. A + 2B → C + E
  5. 5. Which statement about the SN2 mechanism of a primary halogenoalkane is correct?

    • A. It has a carbocation intermediate
    • B. It occurs in two steps
    • C. The nucleophile attacks from the side opposite the halogen
    • D. It is zero order in the nucleophile

Quiz