Structure and bonding of benzene

Structure and bonding of benzene Quiz

Spec 18A · Edexcel A-Level Chemistry: Quiz

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  1. 1. What is the length of each carbon–carbon bond in benzene?

    • A. 0.134 nm
    • B. 0.154 nm
    • C. 0.140 nm, between a single and a double bond
    • D. Three of 0.154 nm and three of 0.134 nm
  2. 2. Benzene has an enthalpy change of hydrogenation of −208 kJ mol⁻¹. The Kekulé structure predicts −360 kJ mol⁻¹. What does this show?

    • A. Benzene is 152 kJ mol⁻¹ more stable than the Kekulé structure
    • B. Benzene is 152 kJ mol⁻¹ less stable than the Kekulé structure
    • C. Benzene has three C=C double bonds
    • D. Benzene has no π electrons
  3. 3. What forms the delocalised π system in benzene?

    • A. Overlap of s orbitals
    • B. End-on overlap of sp³ orbitals
    • C. Overlap of hydrogen orbitals
    • D. Sideways overlap of p orbitals above and below the ring
  4. 4. Why does benzene resist bromination compared with an alkene?

    • A. It has no π electrons
    • B. Its π electron density is delocalised, so lower at any one position
    • C. It has a higher boiling temperature
    • D. It has stronger C–H bonds
  5. 5. What is the C–C–C bond angle in benzene?

    • A. 109.5°
    • B. 180°
    • C. 90°
    • D. 120°

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