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Combustion of FuelsOxford AQA IGCSE Chemistry: Revision notes

Section 1

What is released when fuels burn?

Most fuels contain carbon and/or hydrogen, and may also contain sulfur as an impurity. When a fuel burns, a range of products can be released depending on its composition and how completely it burns:

  • Carbon dioxide (CO2)
  • Water (vapour)
  • Carbon monoxide (CO)
  • Sulfur dioxide (SO2)
  • Oxides of nitrogen
  • Solid particles (particulates, including soot)
Key termsparticulates

Section 2

What environmental problems do these products cause?

Each combustion product causes a different environmental problem:

ProductEnvironmental effect
Sulfur dioxide, oxides of nitrogenCause acid rain
Carbon dioxideIncreased levels may cause climate change
Solid particles (particulates)Cause global dimming (particles in the atmosphere reflect and absorb sunlight)
Key termsacid rainclimate changeglobal dimming
Exam tip

Match each product to its correct environmental problem precisely — examiners penalise mixing up acid rain (SO2/NOx) with climate change (CO2) with global dimming (particulates).

Section 3

What is the difference between complete and incomplete combustion?

  • Complete combustion happens when there is plenty of oxygen. The fuel is fully oxidised, producing only carbon dioxide and water (plus sulfur dioxide if sulfur is present)
  • Incomplete combustion happens when there is insufficient oxygen. This produces carbon monoxide and/or solid carbon (soot/particulates) as well as, or instead of, carbon dioxide
Key termscomplete combustionincomplete combustion
Common mistake

Carbon monoxide is toxic because it is colourless and odourless but stops blood carrying oxygen effectively — this is a common extended-answer point examiners look for.

Section 4

How do the products relate to what is in the fuel?

The products of combustion depend directly on the elements present in the fuel:

  • A fuel containing only carbon and hydrogen (a hydrocarbon) produces carbon dioxide and water (complete combustion), or carbon monoxide/soot and water (incomplete combustion)
  • A fuel containing sulfur as an impurity additionally produces sulfur dioxide
  • Nitrogen oxides usually form from nitrogen and oxygen in the air reacting at the high temperatures reached during combustion, rather than from nitrogen in the fuel itself

Must Know

  • Burning fuels can release CO2, water vapour, CO, SO2, oxides of nitrogen, and particulates
  • SO2 and oxides of nitrogen cause acid rain
  • CO2 is linked to climate change
  • Particulates cause global dimming
  • Complete combustion (plenty of oxygen) gives CO2 and water; incomplete combustion (limited oxygen) gives CO and/or soot
  • The elements present in the fuel (and reaction with air) determine which products form

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