Rate-determining step and reaction mechanisms

Rate-determining step and reaction mechanisms Quiz

Spec 11.6–9 · Edexcel International A Level Chemistry: Quiz

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5 questions, one answer each

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  1. 1. A reaction has rate = k[X]². How many X particles are in the rate-determining step?

    • A. One
    • B. Two
    • C. Three
    • D. None
  2. 2. A mechanism has a slow step A + B → C + D followed by a fast step C + B → E. What is the predicted rate equation?

    • A. rate = k[A]
    • B. rate = k[A][B]²
    • C. rate = k[A][B]
    • D. rate = k[C][B]
  3. 3. A tertiary halogenoalkane is hydrolysed with rate = k[RX]. Which mechanism does this support?

    • A. SN1
    • B. SN2
    • C. Free-radical substitution
    • D. Electrophilic addition
  4. 4. The iodination of propanone is zero order with respect to iodine. What does this show?

    • A. Iodine is in the slow step
    • B. Iodine reacts only after the rate-determining step
    • C. Iodine is the catalyst
    • D. Iodine is not a reactant
  5. 5. What is an intermediate?

    • A. A catalyst that is regenerated
    • B. A species in the overall equation
    • C. A species present only in the slow step
    • D. A species formed in one step and used up in a later step

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