Mass spectrometry in organic analysis

Mass spectrometry in organic analysis Quiz

Spec 3.3.6.2 · AQA A-Level Chemistry: Quiz

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  1. 1. In a mass spectrum the peak with the highest m/z is at 60. What is this peak?

    • A. The molecular ion
    • B. A fragment ion only
    • C. The base peak always
    • D. The carbon-13 peak
  2. 2. Why can high-resolution mass spectrometry distinguish CO from N₂?

    • A. Their whole-number masses differ
    • B. Their precise masses differ because atomic masses are not whole numbers
    • C. CO has a charge but N₂ does not
    • D. N₂ does not form a molecular ion
  3. 3. What is the precise Mᵣ of CH₄O (C = 12.0000, H = 1.0078, O = 15.9949)?

    • A. 32.0000
    • B. 31.0183
    • C. 32.0261
    • D. 32.0360
  4. 4. A compound has a precise Mᵣ of 60.0210. Which formula fits: C₃H₈O (60.0573) or C₂H₄O₂ (60.0210)?

    • A. C₃H₈O
    • B. Neither
    • C. Both
    • D. C₂H₄O₂
  5. 5. Which statement is correct about a precise relative molecular mass?

    • A. It shows the structure of the molecule
    • B. It shows the functional groups present
    • C. It shows the number of isomers
    • D. It shows the molecular formula but not the structure

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